Matches in SemOpenAlex for { <https://semopenalex.org/work/W2104393606> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2104393606 abstract "[5926-35-2] C7H19ClSi2 (MW 194.85) InChI = 1S/C7H19ClSi2/c1-9(2,3)7(8)10(4,5)6/h7H,1-6H3 InChIKey = XNJGZHVYPBNLEB-UHFFFAOYSA-N (versatile C1 building block; broad application in Peterson olefination reactions; Grignard reagent participates readily in Kumada cross-coupling reactions with aryl and vinyl halides; useful in synthesis of methylenephosphine analogs; as sterically demanding ligand for a number of main group and transition metal complexes) Alternative names: chlorobis(trimethylsilyl)methane; bis(trimethylsilyl) methyl chloride; bis(trimethylsilyl)chloromethane; [chloro(trimethylsilyl)methyl]trimethylsilane. Physical Data: bp 57–60 °C (15 mmHg); flash point 48 °C; d 0.892 g mL−1 (25 °C). Solubility: soluble in common organic solvents (DMF, THF, Et2O, CH2Cl2). Form Supplied in: colorless liquid, commercially available. Preparative Method: a convenient one-pot procedure has been developed by Kemp and Cowley in which trimethylsilylchloride reacts with dichloromethane in the presence of nBuLi at −110 °C to give bis(trimethylsilyl)dichloromethane.1 This intermediate is sequentially treated with nBuLi and ethanol to yield chlorobis(trimethylsilyl)methane. A number of other syntheses have been described.2-8 Purification: fractionally distilled through a Vigreaux column.1 Handling, Storage, and Precautions: flammable. Chlorobis(trimethylsilyl)methane is irritating to the eyes, skin, and respiratory system and should only be handled in a well-ventilated fume hood. In addition, proper protective clothing, gloves, and eye/face protection should be worn when title compound is in use. In case of contact with eyes, rinse immediately with water and seek medical advice." @default.
- W2104393606 created "2016-06-24" @default.
- W2104393606 creator A5060945983 @default.
- W2104393606 creator A5078542515 @default.
- W2104393606 date "2010-10-15" @default.
- W2104393606 modified "2023-10-18" @default.
- W2104393606 title "Silane, 1,1′-(Chloromethylene)bis[1,1,1]-trimethyl-" @default.
- W2104393606 cites W1536028302 @default.
- W2104393606 cites W1569875109 @default.
- W2104393606 cites W1603239801 @default.
- W2104393606 cites W1971737140 @default.
- W2104393606 cites W1972357068 @default.
- W2104393606 cites W1986600327 @default.
- W2104393606 cites W1989642011 @default.
- W2104393606 cites W1997833210 @default.
- W2104393606 cites W1998336129 @default.
- W2104393606 cites W2000883516 @default.
- W2104393606 cites W2001239944 @default.
- W2104393606 cites W2005453818 @default.
- W2104393606 cites W2008465127 @default.
- W2104393606 cites W2010500517 @default.
- W2104393606 cites W2019854908 @default.
- W2104393606 cites W2025774706 @default.
- W2104393606 cites W2030336333 @default.
- W2104393606 cites W2031679507 @default.
- W2104393606 cites W2043264909 @default.
- W2104393606 cites W2053168444 @default.
- W2104393606 cites W2062840163 @default.
- W2104393606 cites W2065778328 @default.
- W2104393606 cites W2068014269 @default.
- W2104393606 cites W2075182720 @default.
- W2104393606 cites W2083286034 @default.
- W2104393606 cites W2085793126 @default.
- W2104393606 cites W2093357110 @default.
- W2104393606 cites W2109033916 @default.
- W2104393606 cites W2112251884 @default.
- W2104393606 cites W2144548161 @default.
- W2104393606 cites W2300812898 @default.
- W2104393606 cites W2327508777 @default.
- W2104393606 cites W2335999867 @default.
- W2104393606 cites W2949551296 @default.
- W2104393606 cites W2952026816 @default.
- W2104393606 doi "https://doi.org/10.1002/047084289x.rn01156" @default.
- W2104393606 hasPublicationYear "2010" @default.
- W2104393606 type Work @default.
- W2104393606 sameAs 2104393606 @default.
- W2104393606 citedByCount "0" @default.
- W2104393606 crossrefType "reference-entry" @default.
- W2104393606 hasAuthorship W2104393606A5060945983 @default.
- W2104393606 hasAuthorship W2104393606A5078542515 @default.
- W2104393606 hasConcept C155647269 @default.
- W2104393606 hasConcept C161790260 @default.
- W2104393606 hasConcept C178790620 @default.
- W2104393606 hasConcept C185592680 @default.
- W2104393606 hasConcept C2777000832 @default.
- W2104393606 hasConcept C2777428142 @default.
- W2104393606 hasConcept C2780263894 @default.
- W2104393606 hasConcept C2780400988 @default.
- W2104393606 hasConcept C2780471494 @default.
- W2104393606 hasConcept C2781076698 @default.
- W2104393606 hasConceptScore W2104393606C155647269 @default.
- W2104393606 hasConceptScore W2104393606C161790260 @default.
- W2104393606 hasConceptScore W2104393606C178790620 @default.
- W2104393606 hasConceptScore W2104393606C185592680 @default.
- W2104393606 hasConceptScore W2104393606C2777000832 @default.
- W2104393606 hasConceptScore W2104393606C2777428142 @default.
- W2104393606 hasConceptScore W2104393606C2780263894 @default.
- W2104393606 hasConceptScore W2104393606C2780400988 @default.
- W2104393606 hasConceptScore W2104393606C2780471494 @default.
- W2104393606 hasConceptScore W2104393606C2781076698 @default.
- W2104393606 hasLocation W21043936061 @default.
- W2104393606 hasOpenAccess W2104393606 @default.
- W2104393606 hasPrimaryLocation W21043936061 @default.
- W2104393606 hasRelatedWork W2035068201 @default.
- W2104393606 hasRelatedWork W2040800427 @default.
- W2104393606 hasRelatedWork W2056236330 @default.
- W2104393606 hasRelatedWork W2060806242 @default.
- W2104393606 hasRelatedWork W2134757538 @default.
- W2104393606 hasRelatedWork W2319837958 @default.
- W2104393606 hasRelatedWork W2346804714 @default.
- W2104393606 hasRelatedWork W2397847375 @default.
- W2104393606 hasRelatedWork W2950314649 @default.
- W2104393606 hasRelatedWork W2950428872 @default.
- W2104393606 isParatext "false" @default.
- W2104393606 isRetracted "false" @default.
- W2104393606 magId "2104393606" @default.
- W2104393606 workType "reference-entry" @default.