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- W2104448443 abstract "In a twist: The carboxylate ligand in the clamp of a highly preorganized diferrous site shows temperature-dependent dynamic behavior, coined the “carboxylate twist”. It leads to a fluctuation of the electric field gradient and thus averaged Mössbauer resonances at higher temperatures, resulting in magnetic and spectroscopic hysteresis even without any spin-crossover or valence tautomerism. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W2104448443 date "2012-09-10" @default.
- W2104448443 modified "2023-10-18" @default.
- W2104448443 title "The Carboxylate Twist: Hysteretic Bistability of a High-Spin Diiron(II) Complex Identified by Mössbauer Spectroscopy" @default.
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- W2104448443 doi "https://doi.org/10.1002/anie.201202759" @default.
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