Matches in SemOpenAlex for { <https://semopenalex.org/work/W2104450467> ?p ?o ?g. }
- W2104450467 endingPage "16748" @default.
- W2104450467 startingPage "16748" @default.
- W2104450467 abstract "A simple analytical expression is presented for the study of the first-order catalytic mechanism using Square Wave Voltammetry (SWV) at disc electrodes. These electrodes are extensively used in electrochemical studies but modelling the electrochemical response at this geometry is complex and usually requires the use of sophisticated numerical methods. By contrast, the analytical solution presented in this work is easy to compute and it is applicable to any size of the disc and for arbitrary kinetics of the catalytic reaction. The effects of the electrode size, the homogeneous rate constants, the frequency and the square wave amplitude on the SWV response are analyzed. Criteria are given for the detection of the steady-state response as well as procedures for the extraction of the catalytic rate constant from the value of the peak current. The theory is applied to obtain the kinetics of the reduction of the anion nitrite by an electrogenerated heteropolyanion [P(W3O10)4]4− at gold microdiscs." @default.
- W2104450467 created "2016-06-24" @default.
- W2104450467 creator A5012512740 @default.
- W2104450467 creator A5044732664 @default.
- W2104450467 creator A5057995756 @default.
- W2104450467 creator A5071822932 @default.
- W2104450467 creator A5076368908 @default.
- W2104450467 date "2011-01-01" @default.
- W2104450467 modified "2023-10-09" @default.
- W2104450467 title "Analytical theory of the catalytic mechanism in square wave voltammetry at disc electrodes" @default.
- W2104450467 cites W1882068856 @default.
- W2104450467 cites W1973538754 @default.
- W2104450467 cites W1977423718 @default.
- W2104450467 cites W1980688557 @default.
- W2104450467 cites W1983008142 @default.
- W2104450467 cites W1983673235 @default.
- W2104450467 cites W1990726311 @default.
- W2104450467 cites W1997050209 @default.
- W2104450467 cites W1998368786 @default.
- W2104450467 cites W1999826539 @default.
- W2104450467 cites W2001450217 @default.
- W2104450467 cites W2002510226 @default.
- W2104450467 cites W2003880087 @default.
- W2104450467 cites W2005958769 @default.
- W2104450467 cites W2007189594 @default.
- W2104450467 cites W2009365274 @default.
- W2104450467 cites W2016817534 @default.
- W2104450467 cites W2028981094 @default.
- W2104450467 cites W2031907294 @default.
- W2104450467 cites W2036605572 @default.
- W2104450467 cites W2039714897 @default.
- W2104450467 cites W2048541574 @default.
- W2104450467 cites W2053793827 @default.
- W2104450467 cites W2056340337 @default.
- W2104450467 cites W2060120702 @default.
- W2104450467 cites W2061988076 @default.
- W2104450467 cites W2063173852 @default.
- W2104450467 cites W2064292027 @default.
- W2104450467 cites W2065016187 @default.
- W2104450467 cites W2067893371 @default.
- W2104450467 cites W2071561985 @default.
- W2104450467 cites W2074365275 @default.
- W2104450467 cites W2075420253 @default.
- W2104450467 cites W2079612070 @default.
- W2104450467 cites W2088401654 @default.
- W2104450467 cites W2090285333 @default.
- W2104450467 cites W2094102649 @default.
- W2104450467 cites W2325797499 @default.
- W2104450467 cites W2329111598 @default.
- W2104450467 cites W4247770514 @default.
- W2104450467 cites W48074757 @default.
- W2104450467 doi "https://doi.org/10.1039/c1cp22032b" @default.
- W2104450467 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21858363" @default.
- W2104450467 hasPublicationYear "2011" @default.
- W2104450467 type Work @default.
- W2104450467 sameAs 2104450467 @default.
- W2104450467 citedByCount "40" @default.
- W2104450467 countsByYear W21044504672012 @default.
- W2104450467 countsByYear W21044504672013 @default.
- W2104450467 countsByYear W21044504672014 @default.
- W2104450467 countsByYear W21044504672015 @default.
- W2104450467 countsByYear W21044504672016 @default.
- W2104450467 countsByYear W21044504672017 @default.
- W2104450467 countsByYear W21044504672018 @default.
- W2104450467 countsByYear W21044504672019 @default.
- W2104450467 countsByYear W21044504672020 @default.
- W2104450467 countsByYear W21044504672021 @default.
- W2104450467 countsByYear W21044504672022 @default.
- W2104450467 countsByYear W21044504672023 @default.
- W2104450467 crossrefType "journal-article" @default.
- W2104450467 hasAuthorship W2104450467A5012512740 @default.
- W2104450467 hasAuthorship W2104450467A5044732664 @default.
- W2104450467 hasAuthorship W2104450467A5057995756 @default.
- W2104450467 hasAuthorship W2104450467A5071822932 @default.
- W2104450467 hasAuthorship W2104450467A5076368908 @default.
- W2104450467 hasConcept C113196181 @default.
- W2104450467 hasConcept C121332964 @default.
- W2104450467 hasConcept C135692309 @default.
- W2104450467 hasConcept C147789679 @default.
- W2104450467 hasConcept C148898269 @default.
- W2104450467 hasConcept C161790260 @default.
- W2104450467 hasConcept C165801399 @default.
- W2104450467 hasConcept C17525397 @default.
- W2104450467 hasConcept C178790620 @default.
- W2104450467 hasConcept C185592680 @default.
- W2104450467 hasConcept C2524010 @default.
- W2104450467 hasConcept C2777869211 @default.
- W2104450467 hasConcept C2779603750 @default.
- W2104450467 hasConcept C33923547 @default.
- W2104450467 hasConcept C43617362 @default.
- W2104450467 hasConcept C52859227 @default.
- W2104450467 hasConcept C62520636 @default.
- W2104450467 hasConcept C74650414 @default.
- W2104450467 hasConcept C93391505 @default.
- W2104450467 hasConcept C96352100 @default.
- W2104450467 hasConceptScore W2104450467C113196181 @default.
- W2104450467 hasConceptScore W2104450467C121332964 @default.
- W2104450467 hasConceptScore W2104450467C135692309 @default.