Matches in SemOpenAlex for { <https://semopenalex.org/work/W2104568412> ?p ?o ?g. }
- W2104568412 endingPage "1822" @default.
- W2104568412 startingPage "1816" @default.
- W2104568412 abstract "The variable temperature (298–178 K)1H NMR spectra of tetrahydro-1,4-benzothiazepines 1–10 are described and discussed. Compounds 2–10 exist as two puckered mirror-image (enantiomorphic) conformers, with benzothiazepine ring chair-to-chair interconversion barriers of ca. 10 kcal mol−1 in CD2Cl2 solution. A similar interconversion was detected for compound 1, of lower symmetry. The ground state conformations of 1–10 were assigned on the basis of the magnitudes of 1H–1H vicinal coupling constants. The 1H and 13C NMR spectral assignments were determined by 1H–1H COSY, HETCOR, and NOESY experiments. The stereochemistry and conformation of compound 1 was further confirmed by a single crystal X-ray structure determination." @default.
- W2104568412 created "2016-06-24" @default.
- W2104568412 creator A5019813856 @default.
- W2104568412 creator A5072850791 @default.
- W2104568412 creator A5081848017 @default.
- W2104568412 creator A5082158198 @default.
- W2104568412 date "2002-10-03" @default.
- W2104568412 modified "2023-09-23" @default.
- W2104568412 title "1H and 13C NMR study of tetrahydro-1,4-benzothiazepine conformationsElectronic supplementary information (ESI) available: crystal data, structure refinement and a perspective view of the X-ray crystal structure of 1. See http://www.rsc.org/suppdata/p2/b2/b205768a/" @default.
- W2104568412 cites W1584530142 @default.
- W2104568412 cites W1659869836 @default.
- W2104568412 cites W1975167576 @default.
- W2104568412 cites W1976599248 @default.
- W2104568412 cites W1979259874 @default.
- W2104568412 cites W1986746638 @default.
- W2104568412 cites W1991619240 @default.
- W2104568412 cites W1997310073 @default.
- W2104568412 cites W2000869573 @default.
- W2104568412 cites W2002949852 @default.
- W2104568412 cites W2008531219 @default.
- W2104568412 cites W2015022049 @default.
- W2104568412 cites W2015939437 @default.
- W2104568412 cites W2018449516 @default.
- W2104568412 cites W2027408430 @default.
- W2104568412 cites W2029784811 @default.
- W2104568412 cites W2047562031 @default.
- W2104568412 cites W2049714190 @default.
- W2104568412 cites W2055271776 @default.
- W2104568412 cites W2056865796 @default.
- W2104568412 cites W2059182080 @default.
- W2104568412 cites W2062893568 @default.
- W2104568412 cites W2070735618 @default.
- W2104568412 cites W2073040278 @default.
- W2104568412 cites W2073802644 @default.
- W2104568412 cites W2074900494 @default.
- W2104568412 cites W2078263961 @default.
- W2104568412 cites W2079468422 @default.
- W2104568412 cites W2079707939 @default.
- W2104568412 cites W2080665513 @default.
- W2104568412 cites W2082833800 @default.
- W2104568412 cites W2089740902 @default.
- W2104568412 cites W2094329283 @default.
- W2104568412 cites W2094416340 @default.
- W2104568412 cites W2096409388 @default.
- W2104568412 cites W2141945828 @default.
- W2104568412 cites W2142395508 @default.
- W2104568412 cites W2146099614 @default.
- W2104568412 cites W2148066840 @default.
- W2104568412 cites W2157986221 @default.
- W2104568412 cites W2335014206 @default.
- W2104568412 cites W2949275683 @default.
- W2104568412 cites W2949647873 @default.
- W2104568412 cites W2950728789 @default.
- W2104568412 cites W2951865442 @default.
- W2104568412 cites W3004657043 @default.
- W2104568412 cites W568690484 @default.
- W2104568412 doi "https://doi.org/10.1039/b205768a" @default.
- W2104568412 hasPublicationYear "2002" @default.
- W2104568412 type Work @default.
- W2104568412 sameAs 2104568412 @default.
- W2104568412 citedByCount "3" @default.
- W2104568412 countsByYear W21045684122020 @default.
- W2104568412 countsByYear W21045684122022 @default.
- W2104568412 crossrefType "journal-article" @default.
- W2104568412 hasAuthorship W2104568412A5019813856 @default.
- W2104568412 hasAuthorship W2104568412A5072850791 @default.
- W2104568412 hasAuthorship W2104568412A5081848017 @default.
- W2104568412 hasAuthorship W2104568412A5082158198 @default.
- W2104568412 hasConcept C115624301 @default.
- W2104568412 hasConcept C12713177 @default.
- W2104568412 hasConcept C154945302 @default.
- W2104568412 hasConcept C163111631 @default.
- W2104568412 hasConcept C185592680 @default.
- W2104568412 hasConcept C199360897 @default.
- W2104568412 hasConcept C2781285689 @default.
- W2104568412 hasConcept C41008148 @default.
- W2104568412 hasConcept C71240020 @default.
- W2104568412 hasConcept C8010536 @default.
- W2104568412 hasConceptScore W2104568412C115624301 @default.
- W2104568412 hasConceptScore W2104568412C12713177 @default.
- W2104568412 hasConceptScore W2104568412C154945302 @default.
- W2104568412 hasConceptScore W2104568412C163111631 @default.
- W2104568412 hasConceptScore W2104568412C185592680 @default.
- W2104568412 hasConceptScore W2104568412C199360897 @default.
- W2104568412 hasConceptScore W2104568412C2781285689 @default.
- W2104568412 hasConceptScore W2104568412C41008148 @default.
- W2104568412 hasConceptScore W2104568412C71240020 @default.
- W2104568412 hasConceptScore W2104568412C8010536 @default.
- W2104568412 hasIssue "11" @default.
- W2104568412 hasLocation W21045684121 @default.
- W2104568412 hasOpenAccess W2104568412 @default.
- W2104568412 hasPrimaryLocation W21045684121 @default.
- W2104568412 hasRelatedWork W1977362542 @default.
- W2104568412 hasRelatedWork W1991883810 @default.
- W2104568412 hasRelatedWork W2039374736 @default.
- W2104568412 hasRelatedWork W2119429067 @default.
- W2104568412 hasRelatedWork W2159319742 @default.
- W2104568412 hasRelatedWork W2233838515 @default.