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- W2104573162 abstract "Abstract The complexes trans-[MCl2( SC 2 H 4 SC R2)2] (M = Pd(II) and Pt(II), R = H and Me) have been synthesized and characterized. The energies of pyramidal inversion of the metal-coordinated sulphur atoms, measured by NMR bandshape analyses, are in the range 49–64 kJ mol−1 for the dichloro complexes. NMR observations suggest that for the 1,3-dithiolane complexes (R = H) this pyramidal inversion process is correlated with intramolecular 1,3-metallotropic shifts." @default.
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- W2104573162 date "1988-01-01" @default.
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- W2104573162 title "Nuclear magnetic resonance investigations of the fluxionality of trans-palladium(II) and -platinum(II) dichloride complexes of 1,3-dithiolanes—I. 1,3-Dithiolane and 2,2-dimethyl-1,3-dithiolane complexes" @default.
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- W2104573162 doi "https://doi.org/10.1016/s0277-5387(00)80380-0" @default.
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