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- W2104615215 abstract "This study is directed toward synergistic integration of processing of nylon 66 fibers with solid-state polymerization. The following two goals are sought through the incorporation of solid-state polymerization after the initial shaping operation: eliminating some of the processing problems in the production of high molecular weight, high performance industrial fibers and attainment of improved mechanical properties via high molecular weight. Successful solid-state polymerization has been achieved with as-spun fibers of nylon 66 and molecular weights up to 280,000 g/mol have been obtained from a starting molecular weight of 40,000 g/mol. It is shown that much of the ductility of the starting fiber can be retained, or even enhanced, with solid-state polymerization. Simulated drawing experiments using a thermal deformation analysis technique show an increase in the drawing potential of the solid-state polymerized fiber as compared to the starting material. This has important implications regarding the ultimate properties that can be achieved in fibers of condensation polymers. © 1994 John Wiley & Sons, Inc." @default.
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- W2104615215 date "1994-09-26" @default.
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- W2104615215 title "Solid-state polymerization vis-à-vis fiber formation of step-growth polymers. I. Results from a study of nylon 66" @default.
- W2104615215 doi "https://doi.org/10.1002/app.1994.070531304" @default.
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