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• W2104781244 abstract "Recent measurements of carbon isotopes in carbon dioxide using near-infrared, diode-laser-based cavity ring-down spectroscopy (CRDS) are presented. The CRDS system achieved good precision, often better than 0.2‰, for 4% CO2 concentrations, and also achieved 0.15–0.25‰ precision in a 78 min measurement time with cryotrap-based pre-concentration of ambient CO2 concentrations (360 ppmv). These results were obtained with a CRDS system possessing a data rate of 40 ring-downs per second and a loss measurement of 4.0 × 10−11 cm−1 Hz−1/2. Subsequently, the measurement time has been reduced to under 10 min. This standard of performance would enable a variety of high concentration (3–10%) isotopic measurements, such as medical human breath analysis or animal breath experiments. The extension of this ring-down to the 2 μm region would enable isotopic analysis at ambient concentrations, which, combined with the small size, robust design, and potential for frequent measurements at a remote site, make CRDS technology attractive for remote atmospheric measurement applications." @default.
• W2104781244 created "2016-06-24" @default.
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• W2104781244 date "2006-03-01" @default.
• W2104781244 modified "2023-10-10" @default.
• W2104781244 title "Applications of cavity ring-down spectroscopy to high precision isotope ratio measurement of¹³C/¹²C in carbon dioxide" @default.
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• W2104781244 doi "https://doi.org/10.1080/10256010500502934" @default.
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