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- W2104807546 abstract "Abstract Copper‐catalyzed silylation of aryl allenes using a silylborane reagent affords vinyl silane building blocks with high efficiency. The use of a seven‐membered NHC ligand proved crucial for high regioselectivity. The catalytically generated allylcoppper intermediates were intercepted by aldehydes in a diastereoselective three‐component coupling to furnish homoallylic alcohols." @default.
- W2104807546 created "2016-06-24" @default.
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- W2104807546 date "2014-08-21" @default.
- W2104807546 modified "2023-10-18" @default.
- W2104807546 title "Cu(I)-NHC-Catalyzed Silylation of Allenes: Diastereoselective Three-Component Coupling with Aldehydes" @default.
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- W2104807546 doi "https://doi.org/10.1002/chem.201404330" @default.
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