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• W2104861054 startingPage "6496" @default.
• W2104861054 abstract "DMAP, DBU, and quinuclidine efficiently promote novel hydroalkoxylation reactions of acrylamide in primary alcohol solvents. DABCO is a comparatively poor hydroalkoxylation promoter and can effect clean, selective Baylis−Hillman reactions between acrylamide and aldehydes in alcoholic/aqueous media in which more basic nucleophilic catalysts promote hydroalkoxylation preferentially. Optimization of the reaction conditions has allowed acrylamide to be reacted with a range of aromatic aldehydes in moderate to excellent yields, including the first examples involving deactivated, electron-rich substrates such as p-tolualdehyde and o-anisaldehyde." @default.
• W2104861054 created "2016-06-24" @default.
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• W2104861054 date "2004-08-21" @default.
• W2104861054 modified "2023-10-18" @default.
• W2104861054 title "Acrylamide in the Baylis−Hillman Reaction: Expanded Reaction Scope and the Unexpected Superiority of DABCO over More Basic Tertiary Amine Catalysts" @default.
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• W2104861054 doi "https://doi.org/10.1021/jo0490907" @default.
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