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- W2104861837 abstract "The following molar thermodynamic properties have been determined for ScI3(cr) at T′ = 298.15 K and po = 101.325 kPa: heat capacity, Cp,mo(T′) = (98.95±0.20) J·K−1·mol−1; standard entropy, {Smo(T′)−Smo(0)} = (185.66±0.37) J·K−1·mol−1; standard enthalpy of formation, ΔfHmo(T′) = −(568.74±0.98) kJ·mol−1; and standard Gibbs energy of formation, ΔfGmo(T′) = −(561.79±0.99) kJ·mol−1. For ScI3(cr), the following equations (298.15 K < T < 1225 K) are applicable: enthalpy increment, {Hmo(T)−Hmo(298.15 K)}/(J·mol−1) = −27429.9 + 83.115(TK) + 3.70964 × 10−2(TK)2 − 2.714877 × 10−5(TK)3 + 9.0048124 × 10−9(TK)4; Cp,mo(T)/(J·K−1·mol−1) = 83.115 + 7.41928 × 10−2(TK) − 8.144631 × 10−5(TK)2 + 3.601925 × 10−8(TK)3. For ScI3(l), the following equations (1225 K < T < 1325 K) are applicable: {Hmo(T)−Hmo(298.15 K)}/(J·mol−1) = −349788.4 + 697.909(TK) − 0.2167192(TK)2; Cp,mo(T)/(J·K−1·mol−1) = 697.909 − 0.433438(TK). The molar enthalpy of transition at the melting temperature of 1225 K is (79.51±0.50) kJ·mol−1 and the corresponding molar entropy of melting is (64.91±0.41) J·K−1·mol−1. The thermodynamic properties of ScI3 are tabulated from 298.15 K to 1325 K. The mean bond dissociation enthalpy, 〈Dmo(ScI)〉, is (340.0±1.1) kJ·mol−1 at 298.15 K." @default.
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- W2104861837 date "1987-01-01" @default.
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- W2104861837 title "Calorimetric measurements on high-purity ScI3" @default.
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- W2104861837 doi "https://doi.org/10.1016/0021-9614(87)90165-0" @default.
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