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- W2104892912 abstract "Absorption, ESR and photoluminescence of hexakis(pentamethyldisilyl)disilane [(Me3SiMe2Si)3Si]21 were studied. Two branched polysilyl radicals were observed by ESR spectroscopy under UV irradiation of 1. The smaller ‘star’ radical (Me3SiMe2Si)3Si2 has half-lifetime 1 s whereas the bigger one (Me3SiMe2Si)3Si(Me3SiMe2Si)2Si3 has a half-lifetime about 50 min. During irradiation the reaction 1 → 2 + 3 followed by 2 + 3 → products (P) occur. The behavior of the 300 nm absorption of radical 3 during the irradiation was found to be similar to the radical 3 appearance measured by ESR. The silane (Me3SiMe2Si)3SiH was found as main product (∼50% yield) of the photo-cleavage of the disilane 1." @default.
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- W2104892912 date "2003-06-01" @default.
- W2104892912 modified "2023-10-18" @default.
- W2104892912 title "Spectroscopic studies of the role of silyl radicals in photolysis of polysilanes" @default.
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- W2104892912 doi "https://doi.org/10.1016/s0009-2614(03)00717-6" @default.
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