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- W2104927900 abstract "Investigations to exploit the anion binding induced conformational changes displayed by a new class of acyclic receptor for anion recognition, fluorescence sensing and pseudorotaxane disassembly are described. A series of imidazolium-appended bis-amide-pyridine, pyridine N-oxide and pyridinium containing receptors are synthesised and their anion binding properties elucidated using 1H NMR spectroscopy. Upon anion recognition, the receptors exhibit a substantial conformational change from an ‘open’ to a more ‘closed’ intramolecular geometry. The fluorescence anion sensing ability of a bis-pyrene-functionalised analogue is investigated, with anion-induced responses arising from excimer signalling mechanisms. A pseudorotaxane assembly formed between the pyridine N-oxide receptor acting as a threading component and an isophthalamide macrocycle is demonstrated to undergo disassembly resulting from the conformational behaviour exhibited by the thread upon chloride binding." @default.
- W2104927900 created "2016-06-24" @default.
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- W2104927900 date "2012-01-01" @default.
- W2104927900 modified "2023-09-25" @default.
- W2104927900 title "Anion binding induced conformational changes exploited for recognition, sensing and pseudorotaxane disassembly" @default.
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- W2104927900 doi "https://doi.org/10.1039/c2dt31640d" @default.
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