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- W2104941752 abstract "Chromatography with a supercritical fluid as the mobile phase was suggested more than four decades ago (Klesper, E., Corwin, A. H., Turner, D. A., J. Org. Chem. 1962, 27, 700-701). Supercritical fluid chromatography (SFC) is basically a hybrid of GC and LC that eases the resolution of a mixture of compounds not conveniently resolved by either GC or LC. The mobile phases for SFC have low viscosities and high diffusion coefficients compared to those for HPLC and allow for high efficiency separations. SFC uses supercritical fluid as the mobile phase, polar organic solvents as the modifiers in conjunction with acidic/basic compounds as additives to run the chromatographic process like in HPLC. In many applications, SFC-based methods are advantageous over HPLC-based methods as a separation tool in terms of efficiency and economical impact perspectives. Today, the availability of commercial hardware and API interfaces with a mass spectrometer makes SFC even more widely applicable for chemical analysis in many research fields. This review summarizes a variety of novel SFC-MS methods for chemical analysis that have been reported in the peer-reviewed publications." @default.
- W2104941752 created "2016-06-24" @default.
- W2104941752 creator A5047711440 @default.
- W2104941752 creator A5072485296 @default.
- W2104941752 date "2008-04-30" @default.
- W2104941752 modified "2023-10-09" @default.
- W2104941752 title "Supercritical fluid chromatography-mass spectrometry for chemical analysis" @default.
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- W2104941752 doi "https://doi.org/10.1002/jssc.200700581" @default.
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