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- W2104953912 abstract "Two new cationic mono(pentamethylcyclopentadienyl) organohafnium complexes with η3-2-methallyl ligands, [(C5Me5)Hf(η3-2-C4H7)Me][MeB(C6F5)3] (5) and [(C5Me5)Hf(η3-2-C4H7)2][B(C6F5)4] (6), have been prepared. The former readily polymerises ethene, but is not active towards propene. The latter, with the weakly coordinating [B(C6F5)4] anion, oligomerises propene to atactic oligomers. In contrast with metallocene systems, the oligomerisation of α-olefins like propene is apparently readily initiated on the 2-methallyl groups in this complex." @default.
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- W2104953912 date "1997-04-01" @default.
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- W2104953912 title "Cationic mono(pentamethylcyclopentadienyl)(2-methallyl) complexes of hafnium" @default.
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- W2104953912 doi "https://doi.org/10.1016/s0022-328x(96)06924-0" @default.
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