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- W2104999012 abstract "Differential thermal analysis (DTA) of the melting range of annealed and solution-crystallized low-pressure polyethylene (Marlex 50) has been carried out and found to be comparable in precision with earlier calorimetric determinations. The melting range of the single-crystalline material is shifted by 3.7°C. to lower temperature with respect to the melt-annealed polyethylene. Heat of fusion estimates from the peak height and area of the DTA curves as well as density determinations gave a ratio of about 1.08 for the crystallinities of annealed and single-crystalline polyethylene. The per cent crystallinity calculated from density for annealed polyethylene was found to be 90 ± 3, which is in good accord with calorimetric and x-ray determinations." @default.
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- W2104999012 date "1961-03-01" @default.
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- W2104999012 title "Thermodynamics of crystalline linear high polymers. I. Comparison of the melting transitions of solution and melt-crystallized polyethylene" @default.
- W2104999012 doi "https://doi.org/10.1002/pol.1961.1205015309" @default.
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