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- W2105128797 abstract "[reaction: see text] Reaction of homoallylic alcohols with aldehydes in the presence of TFA gives, after hydrolysis of the ester, 4-hydroxy-2,3,6-trisubstituted tetrahydropyrans with the creation of three new stereocenters in a single-pot process. By varying the aldehyde component, a variety of functionalized side chains are installed at C-2. The utility of this approach is extended to the enantioselective synthesis of tetrahydropyrans with >99% ee." @default.
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- W2105128797 date "2003-06-11" @default.
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- W2105128797 title "Stereoselective Synthesis of 4-Hydroxy-2,3,6-trisubstituted Tetrahydropyrans" @default.
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- W2105128797 doi "https://doi.org/10.1021/ol0346180" @default.
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