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- W2105137768 abstract "Abstract The synthesis of two asymmetrical zinc (II) phthalocyanines (ZnPcs) containing 4-carboxyphenyl and 3-thienyl or 5′-hexyl-2,2′-bithiophene substituent was described. These Zinc Phthalocyanines were synthesized by a statistical condensation reaction between two different phthalonitriles. Each of the phthalonitrile precursors was accomplished by the Suzuki-Miyaura cross-coupling reactions with the aryliodide and corresponding boronic acids. The ZnPc dyes were characterized by MALDI-MS, FT-IR, 1H NMR, UV–Vis, fluorescence and cyclic voltammetry methods. Compared with 3-thienyl substituted ZnPc-1 dye, the Q-band absorption of 5′-Hexyl-2,2′-bithiophene substituted ZnPc-2 was red-shifted by 13 nm because of the extension of π-system. The ZnPc dyes were used as sensitizers in dye-sensitized solar cells (DSSCs). ZnPc-2 sensitized solar cell devices using a 7 (transparent) + 5 (scattering) μm thin TiO2 layer yielded a short-circuit photocurrent density of 3.81 mA/cm2, an open-circuit voltage of 500 mV, and a fill factor of 0.59, corresponding to an overall conversion efficiency of 1.12% under standard AM 1.5 sun light." @default.
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- W2105137768 date "2015-02-01" @default.
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- W2105137768 title "Asymmetric phthalocyanine derivatives containing 4-carboxyphenyl substituents for dye-sensitized solar cells" @default.
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- W2105137768 doi "https://doi.org/10.1016/j.dyepig.2014.09.018" @default.
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