Matches in SemOpenAlex for { <https://semopenalex.org/work/W2105183454> ?p ?o ?g. }
- W2105183454 endingPage "6434" @default.
- W2105183454 startingPage "6430" @default.
- W2105183454 abstract "Abstract A cyclic tetramer of pyrene, [4]cyclo‐2,7‐pyrenylene ([4]CPY), was synthesized from pyrene in six steps and 18 % overall yield by the platinum‐mediated assembly of pyrene units and subsequent reductive elimination of platinum. The structures of the two key intermediates were unambiguously determined by X‐ray crystallographic analysis. DFT calculations showed that the topology of the frontier orbitals in [4]CPY was essentially the same as those in [8]cycloparaphenylene ([8]CPP), and that all the pyrene units were fully conjugated. The electrochemical analyses proved the electronic properties of [4]CPY to be similar to those of [8]CPP. The results are in sharp contrast to those obtained for the corresponding linear oligomers of pyrene in which each pyrene unit was electronically isolated. The results clearly show a novel effect of the cyclic structure on cyclic π‐conjugated molecules." @default.
- W2105183454 created "2016-06-24" @default.
- W2105183454 creator A5008555387 @default.
- W2105183454 creator A5049576123 @default.
- W2105183454 creator A5065378321 @default.
- W2105183454 creator A5081150731 @default.
- W2105183454 creator A5087615219 @default.
- W2105183454 date "2014-05-13" @default.
- W2105183454 modified "2023-10-16" @default.
- W2105183454 title "Synthesis, Characterization, and Properties of [4]Cyclo‐2,7‐pyrenylene: Effects of Cyclic Structure on the Electronic Properties of Pyrene Oligomers" @default.
- W2105183454 cites W1975853346 @default.
- W2105183454 cites W1981941167 @default.
- W2105183454 cites W1981996546 @default.
- W2105183454 cites W1998050972 @default.
- W2105183454 cites W1998064676 @default.
- W2105183454 cites W2001351184 @default.
- W2105183454 cites W2006438423 @default.
- W2105183454 cites W2008353908 @default.
- W2105183454 cites W2013665426 @default.
- W2105183454 cites W2015906725 @default.
- W2105183454 cites W2026952132 @default.
- W2105183454 cites W2030342302 @default.
- W2105183454 cites W2040892355 @default.
- W2105183454 cites W2041563063 @default.
- W2105183454 cites W2045033196 @default.
- W2105183454 cites W2046567107 @default.
- W2105183454 cites W2047173632 @default.
- W2105183454 cites W2059019843 @default.
- W2105183454 cites W2061368971 @default.
- W2105183454 cites W2069787331 @default.
- W2105183454 cites W2070910610 @default.
- W2105183454 cites W2076582986 @default.
- W2105183454 cites W2078128673 @default.
- W2105183454 cites W2092184481 @default.
- W2105183454 cites W2100500546 @default.
- W2105183454 cites W2101535935 @default.
- W2105183454 cites W2111754391 @default.
- W2105183454 cites W2112469449 @default.
- W2105183454 cites W2115801440 @default.
- W2105183454 cites W2116882432 @default.
- W2105183454 cites W2122358027 @default.
- W2105183454 cites W2123302127 @default.
- W2105183454 cites W2124586267 @default.
- W2105183454 cites W2128982734 @default.
- W2105183454 cites W2129948280 @default.
- W2105183454 cites W2130922591 @default.
- W2105183454 cites W2135510361 @default.
- W2105183454 cites W2141255824 @default.
- W2105183454 cites W2142890328 @default.
- W2105183454 cites W2148102068 @default.
- W2105183454 cites W2159764916 @default.
- W2105183454 cites W2162352547 @default.
- W2105183454 cites W2163457381 @default.
- W2105183454 cites W2163841131 @default.
- W2105183454 cites W2164538294 @default.
- W2105183454 cites W2167070006 @default.
- W2105183454 cites W2167579892 @default.
- W2105183454 cites W2171194631 @default.
- W2105183454 cites W2313837806 @default.
- W2105183454 cites W2315616408 @default.
- W2105183454 cites W2316108290 @default.
- W2105183454 cites W2317134831 @default.
- W2105183454 cites W2319931114 @default.
- W2105183454 cites W2320167293 @default.
- W2105183454 cites W2320212969 @default.
- W2105183454 cites W2327363355 @default.
- W2105183454 cites W2327927922 @default.
- W2105183454 cites W4210932016 @default.
- W2105183454 cites W4229998295 @default.
- W2105183454 cites W4232945330 @default.
- W2105183454 cites W4235636170 @default.
- W2105183454 cites W4241888906 @default.
- W2105183454 cites W4242019559 @default.
- W2105183454 cites W4244256929 @default.
- W2105183454 cites W4244853722 @default.
- W2105183454 cites W4248601240 @default.
- W2105183454 doi "https://doi.org/10.1002/anie.201403624" @default.
- W2105183454 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24825604" @default.
- W2105183454 hasPublicationYear "2014" @default.
- W2105183454 type Work @default.
- W2105183454 sameAs 2105183454 @default.
- W2105183454 citedByCount "133" @default.
- W2105183454 countsByYear W21051834542014 @default.
- W2105183454 countsByYear W21051834542015 @default.
- W2105183454 countsByYear W21051834542016 @default.
- W2105183454 countsByYear W21051834542017 @default.
- W2105183454 countsByYear W21051834542018 @default.
- W2105183454 countsByYear W21051834542019 @default.
- W2105183454 countsByYear W21051834542020 @default.
- W2105183454 countsByYear W21051834542021 @default.
- W2105183454 countsByYear W21051834542022 @default.
- W2105183454 countsByYear W21051834542023 @default.
- W2105183454 crossrefType "journal-article" @default.
- W2105183454 hasAuthorship W2105183454A5008555387 @default.
- W2105183454 hasAuthorship W2105183454A5049576123 @default.
- W2105183454 hasAuthorship W2105183454A5065378321 @default.
- W2105183454 hasAuthorship W2105183454A5081150731 @default.
- W2105183454 hasAuthorship W2105183454A5087615219 @default.