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• W2105251323 startingPage "9512" @default.
• W2105251323 abstract "The asymmetric CH insertion of α-diazoesters into 1-alkynes was achieved using chiral cationic guanidinium salts and copper(I) complexes. Optically active 2,4-disubstituted allenoates were generated under mild reaction conditions from various α-diazoesters and 1-alkynes in high yield (up to 99 %) and enantioselectivity (up to 97:3 e.r.). Control experiments excluded the possibility of an asymmetric isomerization of alkynoates." @default.
• W2105251323 created "2016-06-24" @default.
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• W2105251323 date "2015-06-26" @default.
• W2105251323 modified "2023-09-24" @default.
• W2105251323 title "Direct Synthesis of Chiral Allenoates from the Asymmetric CH Insertion of α-Diazoesters into Terminal Alkynes" @default.
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• W2105251323 doi "https://doi.org/10.1002/anie.201501918" @default.
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• W2105251323 hasPublicationYear "2015" @default.
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