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- W2105291930 abstract "Two metal-organic coordination polymers of CoII with the molecular formulae [Co(L1)(tp)(H2O)2]n (1) and [Co(L2)(tp)·H2O]n (2) [L1 = 1, 4-bis(benzimidazole-1-ylmethyl)- benzene; L2 = 1, 1-(1, 4-butanediyl)bis(5, 6-dimethylbenzimidazole); tp = terephthalate] were synthesized and characterized by single-crystal X-ray diffraction studies, infrared spectroscopy (IR), thermogravimetric analysis (TGA), X-ray powder diffraction (XRPD), and elemental analysis. The structure determination of complex 1 reveals a 2D layer with (4, 4) topology, with CoII ions at the nodes connected through tp and L1 co-ligands. Complex 2 is the first example of a four-connected SrAl2 structure type (sra, 42638 topology) with threefold interpenetration in CoII coordination frameworks, forming by bridging L2 and tp co-ligands. In addition, the fluorescence and catalytic performances of the complexes for the degradation of methyl orange were investigated." @default.
- W2105291930 created "2016-06-24" @default.
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- W2105291930 date "2013-06-12" @default.
- W2105291930 modified "2023-09-26" @default.
- W2105291930 title "Cobalt(II)-Terephthalate Frameworks Containing Bis(benzimidazole) Derivative Co-ligands: Syntheses, Crystal Structures, Catalytic and Fluorescence Properties" @default.
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- W2105291930 doi "https://doi.org/10.1002/zaac.201300211" @default.
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