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• W2105299018 startingPage "4066" @default.
• W2105299018 abstract "By designing both the cation and anion to give rise to hydrophobicity and polarity, we have created a new class of ionic liquids that are both hydrophobic and polar. These comprise one component of ionic liquid–water biphasic systems having strong hydrogen bonding characteristics in the presence of water. A series of alkylphosphonium phosphonate-type ILs had differing affinities with water, manifested in their phase behaviour with water according to the hydrophobicity of the cations. In particular, ethylphosphonate salts coupled with tetra-n-hexylphosphonium and tri-n-hexyl-n-octylphosphonium cations had lower critical solution temperature behaviour after mixing with water. Moreover, tetra-n-octylphosphonium ethylphosphonate and n-butylphosphonate exhibited stable phase separation and higher hydrogen bonding characteristics even after mixing with water." @default.
• W2105299018 created "2016-06-24" @default.
• W2105299018 creator A5007812369 @default.
• W2105299018 creator A5057087290 @default.
• W2105299018 date "2013-01-01" @default.
• W2105299018 modified "2023-10-11" @default.
• W2105299018 title "Hydrophobic and polar ionic liquids" @default.
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• W2105299018 doi "https://doi.org/10.1039/c3cp44214d" @default.
• W2105299018 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23403716" @default.
• W2105299018 hasPublicationYear "2013" @default.
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