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- W2105396471 abstract "The first artificially made set of electron acceptors is presented that are derived from a unique platform Cs[3,3′-Co(C2B9H11)2], for which the redox potential of each differs from its predecessor by a fixed amount. The sequence of electron acceptors is made by substituting one, two, or more hydrogen atoms by chlorine atoms, yielding Cs[3,3′-Co(C2B9H11−yCly)(C2B9H11−zClz)]. The higher the number of chlorine substituents, the more prone the platform is to be reduced. The effect is completely additive, so if a single substitution implies a reduction of 0.1 V of the redox potential of the parent complex, then ten substitutions imply a reduction of 1 V." @default.
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- W2105396471 date "2010-04-21" @default.
- W2105396471 modified "2023-10-16" @default.
- W2105396471 title "Additive Tuning of Redox Potential in Metallacarboranes by Sequential Halogen Substitution" @default.
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- W2105396471 doi "https://doi.org/10.1002/chem.200902558" @default.
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