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• W2105402034 endingPage "457" @default.
• W2105402034 startingPage "450" @default.
• W2105402034 abstract "Abstract 1 H, 13 C and 15 N NMR studies of iron(II), ruthenium(II) and osmium(II) tris‐chelated cationic complexes with 2,2′‐bipyridine and 1,10‐phenanthroline of the general formula [M(LL) 3 ] 2+ (M = Fe, Ru, Os; LL = bpy, phen) were performed. Inconsistent literature 1 H signal assignments were corrected. Significant shielding of nitrogen‐adjacent protons [H(6) in bpy, H(2) in phen] and metal‐bonded nitrogens was observed, being enhanced in the series Ru(II) → Os(II) → Fe(II) for 1 H, Fe(II) → Ru(II) → Os(II) for 15 N and bpy → phen for both nuclei. The carbons are deshielded, the effect increasing in the order Ru(II) → Os(II) → Fe(II). Copyright © 2010 John Wiley & Sons, Ltd." @default.
• W2105402034 created "2016-06-24" @default.
• W2105402034 creator A5012733143 @default.
• W2105402034 creator A5030546937 @default.
• W2105402034 creator A5059756040 @default.
• W2105402034 creator A5070616947 @default.
• W2105402034 creator A5087532476 @default.
• W2105402034 date "2010-04-13" @default.
• W2105402034 modified "2023-10-12" @default.
• W2105402034 title "¹H NMR assignment corrections and¹H,¹³C,¹⁵N NMR coordination shifts structural correlations in Fe(II), Ru(II) and Os(II) cationic complexes with 2,2′-bipyridine and 1,10-phenanthroline" @default.
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