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• W2105422659 endingPage "1928" @default.
• W2105422659 startingPage "1924" @default.
• W2105422659 abstract "A metal-free, cationic, reversible addition–fragmentation chain-transfer (RAFT) polymerization was proposed and realized. A series of thiocarbonylthio compounds were used in the presence of a small amount of triflic acid for isobutyl vinyl ether to give polymers with controlled molecular weight of up to 1×105 and narrow molecular-weight distributions (Mw/Mn<1.1). This “living” or controlled cationic polymerization is applicable to various electron-rich monomers including vinyl ethers, p-methoxystyrene, and even p-hydroxystyrene that possesses an unprotected phenol group. A transformation from cationic to radical RAFT polymerization enables the synthesis of block copolymers between cationically and radically polymerizable monomers, such as vinyl ether and vinyl acetate or methyl acrylate." @default.
• W2105422659 created "2016-06-24" @default.
• W2105422659 creator A5003740584 @default.
• W2105422659 creator A5011393219 @default.
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• W2105422659 date "2014-12-15" @default.
• W2105422659 modified "2023-10-04" @default.
• W2105422659 title "Cationic RAFT Polymerization Using ppm Concentrations of Organic Acid" @default.
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• W2105422659 doi "https://doi.org/10.1002/anie.201410858" @default.
• W2105422659 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25511364" @default.
• W2105422659 hasPublicationYear "2014" @default.
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