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- W2105427504 abstract "The effect of doping SrTiO 3 into BiFeO 3 on the magnetic and crystal structure has been explored using powder neutron diffraction for ( 1 − x ) BiFeO 3 – x SrTiO 3 where x =0.2, 0.3, 0.4, 0.6 and 0.8. While the data are not sensitive to the cycloidal component of the magnetic ordering, the evolution of the collinear antiferromagnetic moment of the G-type antiferromagnetic component with T and x has been explored, as have structural parameters. It is found that for x ≤ 0.4 pure phase samples form in the R 3 c cell, and for x =0.8 a non-magnetic Pm 3 ¯ m phase is obtained. The x =0.6 sample gives a mixed phase. Through the R 3 c phase the magnetic structure does not change appreciably apart from the reduction of magnetic moment magnitude with the increasing T and/or x . A simple phase diagram for ( 1 − x ) BiFeO 3 – x SrTiO 3 , where hexagons indicate the rhombohedral R 3 c phase and boxes the cubic phase. Filled symbols indicate magnetic ordering. The black arrow indicates T N for BiFeO 3 . • We have established part of the phase diagram for doping SrTiO 3 into BiFeO 3 . • ( 1 − x ) BiFeO 3 – x SrTiO 3 is isostructural with BiFeO 3 up to x < 0.4 , and cubic for x > 0.85 . • We have examined the evolution of ordered magnetic moment with T and x ." @default.
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- W2105427504 date "2013-11-01" @default.
- W2105427504 modified "2023-10-16" @default.
- W2105427504 title "Crystal and magnetic structure of (x=0.2, 0.3, 0.4 and 0.8)" @default.
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- W2105427504 doi "https://doi.org/10.1016/j.jssc.2013.09.024" @default.
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