FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2105451808> ?p ?o ?g. }

• W2105451808 endingPage "1952" @default.
• W2105451808 startingPage "1948" @default.
• W2105451808 abstract "When subjected to positive ion electrospray ionisation (ESI+) mass spectrometry (MS), indoles with a 3-alkyl substituent show a propensity to form novel [2M-H](+) 'covalently bound dimers'. This process, which appears to be initiated in the nebuliser of the instrument, is mechanistically interesting, analytically useful and potentially significant in organic synthesis.A selection of 2- and 3-substituted indoles have been synthesised and analysed by ESI-MS. The formation of the 'homo' and 'hetero' dimers of these compounds has been investigated using ESI+ mode. The mechanism of formation of the observed 'dimeric' species has been probed by synthesising authentic samples of the dimeric compounds.'Dimeric' species corresponding to [2M-H](+) have been observed for all 3-substituted indoles studied, but not for indoles substituted in just the 2-position. By infusing equimolar mixtures of labelled and unlabelled indoles through the instrument, the expected approximately statistical mixture of homo- and heterodimeric species has been observed. Further experiments have established that this novel dimerisation occurs in the droplets formed in the nebuliser of the instrument.It has been shown that 3-substituted indoles form [2M-H](+) dimers in high abundance in the spray obtained from the nebiliser of an ESI+ instrument. The mechanism for the dimerisation does not involve the known 2M dimeric species that is readily formed in the solution-phase chemistry of indoles." @default.
• W2105451808 created "2016-06-24" @default.
• W2105451808 creator A5017450784 @default.
• W2105451808 creator A5030379566 @default.
• W2105451808 creator A5037648315 @default.
• W2105451808 creator A5043397812 @default.
• W2105451808 creator A5072377380 @default.
• W2105451808 date "2014-07-24" @default.
• W2105451808 modified "2023-09-27" @default.
• W2105451808 title "Novel formation of [2M-H]⁺species in positive electrospray mass spectra of indoles" @default.
• W2105451808 cites W1978216187 @default.
• W2105451808 cites W1979948787 @default.
• W2105451808 cites W1980539965 @default.
• W2105451808 cites W1984870629 @default.
• W2105451808 cites W1988411738 @default.
• W2105451808 cites W1989202995 @default.
• W2105451808 cites W2000282599 @default.
• W2105451808 cites W2030230761 @default.
• W2105451808 cites W2034212717 @default.
• W2105451808 cites W2036940947 @default.
• W2105451808 cites W2040627026 @default.
• W2105451808 cites W2057766095 @default.
• W2105451808 cites W2064769321 @default.
• W2105451808 cites W2068705550 @default.
• W2105451808 cites W2084140887 @default.
• W2105451808 cites W2086824827 @default.
• W2105451808 cites W2092094702 @default.
• W2105451808 cites W2092773862 @default.
• W2105451808 cites W2095873942 @default.
• W2105451808 cites W2116919923 @default.
• W2105451808 cites W2132797653 @default.
• W2105451808 cites W2135524878 @default.
• W2105451808 cites W2156737907 @default.
• W2105451808 cites W2170676214 @default.
• W2105451808 cites W2314070077 @default.
• W2105451808 cites W2345580276 @default.
• W2105451808 cites W2950974980 @default.
• W2105451808 doi "https://doi.org/10.1002/rcm.6976" @default.
• W2105451808 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25088138" @default.
• W2105451808 hasPublicationYear "2014" @default.
• W2105451808 type Work @default.
• W2105451808 sameAs 2105451808 @default.
• W2105451808 citedByCount "8" @default.
• W2105451808 countsByYear W21054518082017 @default.
• W2105451808 countsByYear W21054518082019 @default.
• W2105451808 countsByYear W21054518082021 @default.
• W2105451808 countsByYear W21054518082022 @default.
• W2105451808 countsByYear W21054518082023 @default.
• W2105451808 crossrefType "journal-article" @default.
• W2105451808 hasAuthorship W2105451808A5017450784 @default.
• W2105451808 hasAuthorship W2105451808A5030379566 @default.
• W2105451808 hasAuthorship W2105451808A5037648315 @default.
• W2105451808 hasAuthorship W2105451808A5043397812 @default.
• W2105451808 hasAuthorship W2105451808A5072377380 @default.
• W2105451808 hasConcept C145148216 @default.
• W2105451808 hasConcept C155647269 @default.
• W2105451808 hasConcept C162356407 @default.
• W2105451808 hasConcept C178790620 @default.
• W2105451808 hasConcept C180577832 @default.
• W2105451808 hasConcept C185592680 @default.
• W2105451808 hasConcept C194451485 @default.
• W2105451808 hasConcept C2778689049 @default.
• W2105451808 hasConcept C2780263894 @default.
• W2105451808 hasConcept C40325409 @default.
• W2105451808 hasConcept C40684141 @default.
• W2105451808 hasConcept C43617362 @default.
• W2105451808 hasConcept C71240020 @default.
• W2105451808 hasConcept C8010536 @default.
• W2105451808 hasConceptScore W2105451808C145148216 @default.
• W2105451808 hasConceptScore W2105451808C155647269 @default.
• W2105451808 hasConceptScore W2105451808C162356407 @default.
• W2105451808 hasConceptScore W2105451808C178790620 @default.
• W2105451808 hasConceptScore W2105451808C180577832 @default.
• W2105451808 hasConceptScore W2105451808C185592680 @default.
• W2105451808 hasConceptScore W2105451808C194451485 @default.
• W2105451808 hasConceptScore W2105451808C2778689049 @default.
• W2105451808 hasConceptScore W2105451808C2780263894 @default.
• W2105451808 hasConceptScore W2105451808C40325409 @default.
• W2105451808 hasConceptScore W2105451808C40684141 @default.
• W2105451808 hasConceptScore W2105451808C43617362 @default.
• W2105451808 hasConceptScore W2105451808C71240020 @default.
• W2105451808 hasConceptScore W2105451808C8010536 @default.
• W2105451808 hasIssue "17" @default.
• W2105451808 hasLocation W21054518081 @default.
• W2105451808 hasLocation W21054518082 @default.
• W2105451808 hasOpenAccess W2105451808 @default.
• W2105451808 hasPrimaryLocation W21054518081 @default.
• W2105451808 hasRelatedWork W1981053044 @default.
• W2105451808 hasRelatedWork W1984744703 @default.
• W2105451808 hasRelatedWork W2004645109 @default.
• W2105451808 hasRelatedWork W2047260930 @default.
• W2105451808 hasRelatedWork W2078332880 @default.
• W2105451808 hasRelatedWork W2089685911 @default.
• W2105451808 hasRelatedWork W2150844241 @default.
• W2105451808 hasRelatedWork W2389968534 @default.
• W2105451808 hasRelatedWork W2392405928 @default.
• W2105451808 hasRelatedWork W2793834590 @default.
• W2105451808 hasVolume "28" @default.

• next