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- W2105563669 abstract "The crystal structures of Nd 0.7 Ti 0.9 Al 0.1 O 3 , taken to represent the ideal Nd 2/3 TiO 3 , have been elucidated from 4 to 1273 K using high-resolution neutron powder diffraction in combination with group-theoretical analysis. The room-temperature structure is monoclinic in C 2/ m , on a cell with a = 7.6764 (1), b = 7.6430 (1), c = 7.7114 (1) Å, β = 90.042 (2)°. Pertinent features are the layered ordering of the A -site Nd cations/vacancies along the z axis and out-of-phase tilting of the (Ti/Al)O 6 octahedra around both the x and z axes. From about 750 to 1273 K, the octahedra are tilted around just one axis ( x axis) perpendicular to the direction of the cation ordering, giving rise to an orthorhombic structure with space-group symmetry Cmmm ." @default.
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- W2105563669 date "2006-01-17" @default.
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- W2105563669 title "Structures of the cation-deficient perovskite Nd<sub>0.7</sub>Ti<sub>0.9</sub>Al<sub>0.1</sub>O<sub>3</sub> from high-resolution neutron powder diffraction in combination with group-theoretical analysis" @default.
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- W2105563669 doi "https://doi.org/10.1107/s0108768105041066" @default.
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