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- W2105605825 abstract "Treatment of an N-fused [24]pentaphyrin with POCl3 in the presence of triethylamine gave a triply-fused pentaphyrin PO complex through an N-fusion reaction and oxidative C–C bond formation between the pyrrolic β-positions. This complex displays strong antiaromatic character due to its 24π-electronic network as evinced by its 1H NMR chemical shifts, absorption spectrum, and NICS calculation. The PO complex was reduced with BH3·SMe2 to provide P–BH3 complex with concurrent hydrogenation at the pyrrolic β-positions as a rare case of porphyrinoid P(III) complex." @default.
- W2105605825 created "2016-06-24" @default.
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- W2105605825 date "2012-01-01" @default.
- W2105605825 modified "2023-09-24" @default.
- W2105605825 title "Phosphorus complexes of a triply-fused [24]pentaphyrin" @default.
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- W2105605825 doi "https://doi.org/10.1039/c1sc00653c" @default.
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