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• W2105673663 abstract "Two new oxamido-bridged N4 macrocyclic complexes [(CuL)2Mn(C2H5OH)2](ClO4)2·2C2H5OH (1) and [(CuL)2Co-(C2H5OH)2](ClO4)2·2C2H5OH (2) (H2L = 2,3-dioxo-5,6:14,15-di-benzo-7,13-diphenyl-1,4,8,12-tetraazacyclo-pentadeca-7,13-diene) have been synthesized and structurally characterized by X-ray crystallographic investigations. In the two complexes, all copper(II) ions adopt a slightly distorted square-planar configuration and the central manganese(II) and cobalt(II) ions are set in a distorted octahedral coordination sphere, connected to the other CuL fragments through exo-cis oxamido bridges. The analyses of the magnetic properties were carried out by means of the theoretical expression of the magnetic susceptibility deduced from the spin Hamiltonian Ĥ = –2JŜ1Ŝ2, leading to J = –14.58 cm–1 for complex 1 and J = –26.95 cm–1 for complex 2, respectively." @default.
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• W2105673663 date "2009-07-01" @default.
• W2105673663 modified "2023-09-22" @default.
• W2105673663 title "Oxamido-bridged N4Macrocyclic Complexes CuII/MII/CuII(M = Mn, Co): Synthesis, Crystal Structures and Magnetic Properties" @default.
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• W2105673663 doi "https://doi.org/10.1002/zaac.200801280" @default.
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