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- W2105687906 abstract "A series of racemic chiral ortho substituents on 1-phenylhex-1-yne have been found to control the atroposelective formation of a biaryl from Dötz benzannulation with pentacarbonyl(methoxyphenylmethylene)chromium(0). The results show there is a subtle balance between the chiral ortho substituent controlling atroposelectivity with a dr 3–5:1 and allowing benzannulation to proceed in yields of 44–67%." @default.
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- W2105687906 date "2003-10-01" @default.
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- W2105687906 title "Studies into diastereoselective Dötz benzannulations for the synthesis of axially chiral biaryls" @default.
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- W2105687906 doi "https://doi.org/10.1016/j.tetlet.2003.08.096" @default.
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