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• W2105701029 abstract "Treating readily available α-diazo-β-ketoesters with HBF4 results in nucleophilic fluorination by the usually inert and stable tetrafluoroborate anion. The resulting α-fluoro-β-ketoesters are highly versatile synthetic intermediates, for example in the preparation of fluoro-heterocycles, as illustrated by the direct formation of fluoro-pyrimidines, -pyrazoles and -coumarins in a single step." @default.
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• W2105701029 date "2012-01-01" @default.
• W2105701029 modified "2023-10-16" @default.
• W2105701029 title "Nucleophilic fluorination of β-ketoester derivatives with HBF4" @default.
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• W2105701029 doi "https://doi.org/10.1039/c2cc37284c" @default.
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