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- W2105770587 abstract "The reversible micellization and sol–gel transition of block copolymer solutions in an ionic liquid (IL) triggered by a photostimulus is described. The ABA triblock copolymer employed, denoted P(AzoMA-r-NIPAm)-b-PEO-b-P(AzoMA-r-NIPAm)), has a B block composed of an IL-soluble poly(ethylene oxide) (PEO). The A block consists of a random copolymer including thermosensitive N-isopropylacrylamide (NIPAm) units and a methacrylate with an azobenzene chromophore in the side chain (AzoMA). A phototriggered reversible unimer-to-micelle transition of a dilute ABA triblock copolymer (1 wt %) was observed in an IL, 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim]PF6), at an intermediate “bistable” temperature (50 °C). The system underwent a reversible sol–gel transition cycle at the bistable temperature (53 °C), with reversible association/fragmentation of the polymer network resulting from the phototriggered self-assembly of the ABA triblock copolymer (20 wt %) in [C4mim]PF6." @default.
- W2105770587 created "2016-06-24" @default.
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- W2105770587 date "2015-01-22" @default.
- W2105770587 modified "2023-09-30" @default.
- W2105770587 title "Photoreversible Gelation of a Triblock Copolymer in an Ionic Liquid" @default.
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- W2105770587 doi "https://doi.org/10.1002/anie.201411526" @default.
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