Matches in SemOpenAlex for { <https://semopenalex.org/work/W2105794894> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2105794894 endingPage "952" @default.
- W2105794894 startingPage "947" @default.
- W2105794894 abstract "Complexes cis,trans-[MI(Me)(CO)2(PMe3)2] (M = Fe 1a or Ru 1b), in CH2Cl2, reacted with K[(pz)2BH2] and Na[(pz)3BH] affording the acetyl complexes trans-[M(COMe){(pz)2BH2}(CO)(PMe3)2] 2a and 2b and trans-[M(COMe){κ2-(pz)3BH}(CO)(PMe3)2] 3a and 3b, respectively. If the reactions are carried out in polar solvents decomposition of both starting materials occurs. Upon standing in n-hexane solution, the free pyrazol-1-yl arm in complex 3a displaces a co-ordinated PMe3 forming [Fe(COMe){κ3-(pz)3BH}(CO)(PMe3)] 4a. The analogous ruthenium complex was formed directly from the tricarbonyl complex fac-[RuI(Me)(CO)3(PMe3)] 5 with Na[(pz)3BH]. One of the intermediates of the decomposition of a pyrazolyl donor, trans-[Fe(COMe){κ2-(mpz)OB(C8H14)}(CO)(PMe3)2] 6 (mpz = 3-methylpyrazolyl), was isolated from the reaction of 1a with K[(mpz)2B(C8H14)]. This complex was fully characterised both in solution (IR, multinuclear and multidimensional NMR spectroscopy) and in the solid state (X-ray single-crystal diffraction)." @default.
- W2105794894 created "2016-06-24" @default.
- W2105794894 creator A5015211995 @default.
- W2105794894 creator A5041537291 @default.
- W2105794894 creator A5046771754 @default.
- W2105794894 creator A5047494910 @default.
- W2105794894 creator A5056318186 @default.
- W2105794894 creator A5061216046 @default.
- W2105794894 date "1998-01-01" @default.
- W2105794894 modified "2023-09-23" @default.
- W2105794894 title "Synthesis and characterisation of bis- and tris-(pyrazol-1-yl)borate acetyl complexes of FeII and RuII and isolation of an intermediate of B–N bond hydrolysis" @default.
- W2105794894 cites W1967243375 @default.
- W2105794894 cites W1973124843 @default.
- W2105794894 cites W1973433603 @default.
- W2105794894 cites W1985888250 @default.
- W2105794894 cites W1990536808 @default.
- W2105794894 cites W1999996560 @default.
- W2105794894 cites W2006378565 @default.
- W2105794894 cites W2010851420 @default.
- W2105794894 cites W2017519239 @default.
- W2105794894 cites W2018007678 @default.
- W2105794894 cites W2020888695 @default.
- W2105794894 cites W2028972494 @default.
- W2105794894 cites W2041427545 @default.
- W2105794894 cites W2044844614 @default.
- W2105794894 cites W2070995583 @default.
- W2105794894 cites W2085823437 @default.
- W2105794894 cites W2148062424 @default.
- W2105794894 cites W2949400489 @default.
- W2105794894 cites W595635378 @default.
- W2105794894 doi "https://doi.org/10.1039/a708291f" @default.
- W2105794894 hasPublicationYear "1998" @default.
- W2105794894 type Work @default.
- W2105794894 sameAs 2105794894 @default.
- W2105794894 citedByCount "31" @default.
- W2105794894 countsByYear W21057948942012 @default.
- W2105794894 countsByYear W21057948942017 @default.
- W2105794894 countsByYear W21057948942018 @default.
- W2105794894 countsByYear W21057948942019 @default.
- W2105794894 countsByYear W21057948942020 @default.
- W2105794894 countsByYear W21057948942021 @default.
- W2105794894 countsByYear W21057948942022 @default.
- W2105794894 crossrefType "journal-article" @default.
- W2105794894 hasAuthorship W2105794894A5015211995 @default.
- W2105794894 hasAuthorship W2105794894A5041537291 @default.
- W2105794894 hasAuthorship W2105794894A5046771754 @default.
- W2105794894 hasAuthorship W2105794894A5047494910 @default.
- W2105794894 hasAuthorship W2105794894A5056318186 @default.
- W2105794894 hasAuthorship W2105794894A5061216046 @default.
- W2105794894 hasConcept C115624301 @default.
- W2105794894 hasConcept C124681953 @default.
- W2105794894 hasConcept C155647269 @default.
- W2105794894 hasConcept C161790260 @default.
- W2105794894 hasConcept C178790620 @default.
- W2105794894 hasConcept C185592680 @default.
- W2105794894 hasConcept C2781014771 @default.
- W2105794894 hasConcept C501308230 @default.
- W2105794894 hasConcept C55493867 @default.
- W2105794894 hasConcept C555196967 @default.
- W2105794894 hasConcept C66974803 @default.
- W2105794894 hasConcept C71240020 @default.
- W2105794894 hasConcept C8010536 @default.
- W2105794894 hasConcept C94412978 @default.
- W2105794894 hasConceptScore W2105794894C115624301 @default.
- W2105794894 hasConceptScore W2105794894C124681953 @default.
- W2105794894 hasConceptScore W2105794894C155647269 @default.
- W2105794894 hasConceptScore W2105794894C161790260 @default.
- W2105794894 hasConceptScore W2105794894C178790620 @default.
- W2105794894 hasConceptScore W2105794894C185592680 @default.
- W2105794894 hasConceptScore W2105794894C2781014771 @default.
- W2105794894 hasConceptScore W2105794894C501308230 @default.
- W2105794894 hasConceptScore W2105794894C55493867 @default.
- W2105794894 hasConceptScore W2105794894C555196967 @default.
- W2105794894 hasConceptScore W2105794894C66974803 @default.
- W2105794894 hasConceptScore W2105794894C71240020 @default.
- W2105794894 hasConceptScore W2105794894C8010536 @default.
- W2105794894 hasConceptScore W2105794894C94412978 @default.
- W2105794894 hasIssue "6" @default.
- W2105794894 hasLocation W21057948941 @default.
- W2105794894 hasOpenAccess W2105794894 @default.
- W2105794894 hasPrimaryLocation W21057948941 @default.
- W2105794894 hasRelatedWork W2034305746 @default.
- W2105794894 hasRelatedWork W2043509171 @default.
- W2105794894 hasRelatedWork W2050960821 @default.
- W2105794894 hasRelatedWork W2060332114 @default.
- W2105794894 hasRelatedWork W2063038612 @default.
- W2105794894 hasRelatedWork W2067793835 @default.
- W2105794894 hasRelatedWork W2072083970 @default.
- W2105794894 hasRelatedWork W2078266776 @default.
- W2105794894 hasRelatedWork W2950221418 @default.
- W2105794894 hasRelatedWork W2952734099 @default.
- W2105794894 isParatext "false" @default.
- W2105794894 isRetracted "false" @default.
- W2105794894 magId "2105794894" @default.
- W2105794894 workType "article" @default.