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- W2105799165 abstract "Ascorbic acid (vitamin C) has been used as a radical initiator in a metal-free direct CH arylation of (hetero)arenes. Starting from an aniline, the corresponding arenediazonium ion is generated in situ and immediately reduced by vitamin C to an aryl radical that undergoes a homolytic aromatic substitution with a (hetero)arene. Notably, neither heating nor irradiation is required. This procedure is mild, operationally simple, and constitutes a greener approach to arylation." @default.
- W2105799165 created "2016-06-24" @default.
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- W2105799165 date "2014-01-22" @default.
- W2105799165 modified "2023-10-14" @default.
- W2105799165 title "Ascorbic Acid as an Initiator for the Direct CH Arylation of (Hetero)arenes with Anilines Nitrosated In Situ" @default.
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- W2105799165 doi "https://doi.org/10.1002/anie.201309761" @default.
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