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• W2105908710 abstract "The first catalytic asymmetric addition of TosMIC to unactivated ketones is presented. A combination of Me2Zn and aminoalcohol catalyst promoted the aldol addition/cyclization reaction to render oxazolines possessing a fully substituted stereocenter with excellent yields (up to 92%), high enantioselectivities (up to 96%), and complete diastereoselectivity. The chiral oxazolines were then used to give, after a straightforward acid hydrolysis, enantioenriched building blocks bearing tertiary alcohol motifs such as hydroxylaldehydes, hydroxylacids, and hydroxylesters without racemization." @default.
• W2105908710 created "2016-06-24" @default.
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• W2105908710 date "2015-11-23" @default.
• W2105908710 modified "2023-09-23" @default.
• W2105908710 title "Me ₂ Zn‐Mediated Catalytic Enantio‐ and Diastereoselective Addition of TosMIC to Ketones" @default.
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• W2105908710 doi "https://doi.org/10.1002/chem.201504362" @default.
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