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- W2106017243 abstract "This paper describes the orientation of cylindrical domains in thin films of a polystyrene–poly(methylmethacrylate) diblock copolymer (PS-b-PMMA; 0.3 as the PMMA volume fraction) on gold and oxide-coated Si substrates having different surface roughness. Atomic force microscopy images of PS-b-PMMA films having thickness similar to the domain periodicity permitted us to study the effects of substrate roughness and block affinity on domain orientation. PS-b-PMMA films on gold substrates showed metastable vertical domain orientation that was attained more slowly on rougher substrates. In contrast, the domains were horizontally oriented on oxide-coated Si regardless of surface roughness and the annealing conditions examined. In addition, cyclic voltammetry data for PS-b-PMMA films on gold substrates whose PMMA domains were etched suggested that the metastable vertically oriented domains reached the underlying substrates. These results indicate that PS-b-PMMA films containing vertically oriented cylindrical domains can be obtained by using rough gold substrates upon annealing under controlled conditions." @default.
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- W2106017243 date "2009-05-01" @default.
- W2106017243 modified "2023-10-18" @default.
- W2106017243 title "Effects of substrate roughness on the orientation of cylindrical domains in thin films of a polystyrene–poly(methylmethacrylate) diblock copolymer studied using atomic force microscopy and cyclic voltammetry" @default.
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- W2106017243 doi "https://doi.org/10.1016/j.polymer.2009.03.002" @default.
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