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• W2106074067 abstract "Nach Untersuchungen von Fritz u. a. [10] wird in 1,2-Dimethoxyethan oder Bis(2-methoxyethyl)ether Metal Derivatives of Molecular Compounds. VIII. catena-Poly[(2,5,8-trioxanonane-O2,O5) lithium-methylphosphanide] — a Compound with a meso-Helix Structure Studies of Fritz et al. [10] showed methylphosphane to be lithiated at −60°C in 1,2-dimethoxyethane or bis(2-methoxyethyl) ether solution by stoichiometric amounts of lithium n-butanide in n-hexane. After removing the hydrocarbons almost completely by distillation and cooling the solutions to −60°C again, colourless square crystals of (1,2-dimethoxyethane-O,O′)lithium (1) and (2,5,8-trioxanonane-O2,O5)lithium methylphosphanide (2) precipitate. As shown by an X-ray structure determination (monoclinic, P21/n; a = 805.5(1); b = 1820.6(2); c = 851.5(1) pm; β = 116.76(1)° at −100 ± 3°C; Z = 4 formula units; R = 0.034) complex 2 forms a polymer which has the shape of an up to now scarcely noted meso-helix. Four-coordinated lithium is bound to two phosphorus (PLi 252.9 and 253.2 pm; PLiP 131.8°; LiPLi 132.1°) and to two oxygen atoms (LiO 203.9 and 206.8; O …︁ O 270.7 pm; OLiO 82.5°) of the inherently tridentate 2,5,8-trioxanonane ligand. As compared to the standard value (185 pm) the PC distance (187.4 pm) is slightly lengthened. Structure determinations of (2,5,8-trioxanonane-O2,O5,O8) lithium 1-(phenylsulfonyl)alkyl compounds published some years ago [26, 27], allow a comparison of molecular parameters characteristic for the twofold or threefold coordinating chelate ligand." @default.
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• W2106074067 date "1994-08-01" @default.
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• W2106074067 title "Metallderivate von Molek�lverbindungen. VIII.catena-Poly[(2,5,8-trioxanonan-O2,O5) lithium-methylphosphanid] ? eine Verbindung mitmeso-Helix-Struktur" @default.
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• W2106074067 doi "https://doi.org/10.1002/zaac.19946200810" @default.
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