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- W2106084867 abstract "The effects of repeated large strain shear cycles on the dynamics of a glassy acrylate polymer are investigated using an original contact method. It is based on the measurement of the shear properties of thin (about 50 μm) polymer films geometrically confined within contacts between elastic substrates. Under small amplitude (300 nm–10 μm) oscillating lateral displacements, friction at the contact interface can be neglected and the measurement of the contact lateral response thus provides information about the rheology of the sheared polymer film. Using this approach, the complex shear modulus of the polymer film can be measured both in the linear (viscoelastic) and in the nonlinear regimes. The investigations are focused on the changes in mechanical properties induced in a large strain regime where the polymer glass is cyclically sheared up to the yield point. During the application of large strain cycles, the mechanical response of the polymer glass slowly evolves toward a quasi stabilized state which is described from the measurement of an apparent–strain dependent–complex shear modulus. When the applied strain is increased by a tenfold factor, this apparent shear modulus decreases by about one decade. These underlying changes are investigated from a consideration of the time dependent linear viscoelastic properties after the mechanical stimulus. Both mechanical rejuvenation and recovery (ageing) effects are evidenced. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011" @default.
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- W2106084867 date "2011-03-09" @default.
- W2106084867 modified "2023-09-25" @default.
- W2106084867 title "Cyclic nonlinear behavior of a glassy polymer using a contact method" @default.
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- W2106084867 doi "https://doi.org/10.1002/polb.22215" @default.
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