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- W2106087913 abstract "Abstract A variety of unsaturated thioethers have been subjected to cross‐coupling reactions with functionalized zinc reagents in the presence of a transition‐metal catalyst. Three different catalytic systems based on Pd(OAc) 2 or [Ni(acac) 2 ] and the ligands S‐Phos or DPE‐Phos gave the best results. N‐Heterocyclic thioethers based on a pyridine, pyrimidine, pyrazine, pyridazine, triazine, benzothiazole, benzoxazole, pyrrole, or quinazoline ring, as well as thiomethylacetylenes, serve as electrophiles in this cross‐coupling reaction. Aryl‐, heteroaryl‐, benzylic, and alkylzinc halides with sensitive functionalities, such as ester, nitrile, or ketone groups react at ambient temperature with unsaturated thioethers using a Ni catalyst. The corresponding Pd‐catalyzed reactions require slightly higher temperatures. Large‐scale cross‐coupling experiments (10–20 mmol) with N‐heterocycles are also reported." @default.
- W2106087913 created "2016-06-24" @default.
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- W2106087913 date "2011-01-30" @default.
- W2106087913 modified "2023-10-18" @default.
- W2106087913 title "Pd- and Ni-Catalyzed Cross-Coupling Reactions of Functionalized Organozinc Reagents with Unsaturated Thioethers" @default.
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- W2106087913 doi "https://doi.org/10.1002/chem.201002850" @default.
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