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- W2106340071 abstract "A variety of α-aroylacetones 4a−g have been prepared in excellent yields following a new protocol wherein α-aminonitriles 1a−g as the aryl acyl anion equivalents readily react with propargyl bromide as the α-bromoacetone equivalent. The alkylated product undergoes one-pot unmasking of the keto functionality along with Markovnikov's hydration of the terminal alkyne with CuSO4·5H2O in aqueous methanol at 60 °C to furnish the desired target in excellent isolated yields." @default.
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- W2106340071 date "2005-11-24" @default.
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- W2106340071 title "Propargyl Bromide as an Excellent α-Bromoacetone Equivalent: Convenient and New Route to α-Aroylacetones" @default.
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- W2106340071 doi "https://doi.org/10.1021/jo051538w" @default.
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