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- W2106511410 abstract "Methyl β-d-galactopyranosyl-(1→4)-α-d-mannopyranoside methanol 0.375-solvate, C13H24O11·0.375CH3OH, (I), was crystallized from a methanol–ethanol solvent system in a glycosidic linkage conformation, with φ′ (O5Gal—C1Gal—O1Gal—C4Man) = −68.2 (3)° and ψ′ (C1Gal—O1Gal—C4Man—C5Man) = −123.9 (2)°, where the ring is defined by atoms O5/C1–C5 (monosaccharide numbering); C1 denotes the anomeric C atom and C6 the exocyclic hydroxymethyl C atom in the βGalp and αManp residues, respectively. The linkage conformation in (I) differs from that in crystalline methyl α-lactoside [methyl β-d-galactopyranosyl-(1→4)-α-d-glucopyranoside], (II) [Pan, Noll & Serianni (2005). Acta Cryst. C61, o674–o677], where φ′ is −93.6° and ψ′ is −144.8°. An intermolecular hydrogen bond exists between O3Man and O5Gal in (I), similar to that between O3Glc and O5Gal in (II). The structures of (I) and (II) are also compared with those of their constituent residues, viz. methyl α-d-mannopyranoside, methyl α-d-glucopyranoside and methyl β-d-galactopyranoside, revealing significant differences in the Cremer–Pople puckering parameters, exocyclic hydroxymethyl group conformations and intermolecular hydrogen-bonding patterns." @default.
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- W2106511410 date "2010-01-15" @default.
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- W2106511410 title "Methyl 4-<i>O</i>-β-<scp>D</scp>-galactopyranosyl α-<scp>D</scp>-mannopyranoside methanol 0.375-solvate" @default.
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- W2106511410 doi "https://doi.org/10.1107/s0108270109055012" @default.
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