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- W2106520787 abstract "Abstract Chlorosulfonated polyethylene, introduced in 1951, represents a family of chlorinated polymers based on various types of polyolefins and some prefunctionalized resins. They are usually prepared by simultaneous chlorination and chlorosulfonation in a homogeneous solution with an inert solvent. Introduction of chlorine atoms onto the polyolefin chain interrupts its regularity, converting the crystalline polymer into semiplastic, elastomeric, or rigid plastic consistency, depending on the level and distribution of chlorine atoms. The sulfonyl chloride group provides a site for a variety of cross‐linking reactions for thermoset applications. Raw polymer processing and vulcanizate mechanical properties depend on the base resin parameters of molecular weight, molecular weight distribution, and density, in addition to the chlorine and cross‐link type. When properly compounded and cross‐linked, these polymers give superior resistance to oil, heat, and ozone compared to most other elastomers, making them valuable in many automotive, construction, and coating applications. Specific adhesion characteristics of the sulfonyl chloride group and other functionality, eg, maleic anhydride graft, leads to special applications as primers and binders." @default.
- W2106520787 created "2016-06-24" @default.
- W2106520787 creator A5012167640 @default.
- W2106520787 date "2001-10-22" @default.
- W2106520787 modified "2023-10-14" @default.
- W2106520787 title "Ethylene Polymers, Chlorosulfonated" @default.
- W2106520787 cites W1995701673 @default.
- W2106520787 doi "https://doi.org/10.1002/0471440264.pst409" @default.
- W2106520787 hasPublicationYear "2001" @default.
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