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- W2106577799 abstract "The molar heat capacities at constant pressure of small single crystals of α-monoclinic selenium are measured by applying a heat pulse technique in the temperature range 3 to 300 K. Below 5 K the molar heat as a function of temperature obeys Debye's T3-law yielding a Debye temperature θD = 128.3 K. The molar heat at constant volume can be described over the entire temperature range by applying a combination of Debye- and Einstein-terms for the frequency distribution function, with respect to the ring molecular structure of monoclinic selenium. Furthermore, values of thermodynamic functions are calculated. By combining the results of this investigation and data on trigonal selenium given by Chang and Bestful the Gibbs free energy of conversion is obtained. This calculation shows that α-monoclinic selenium is unstable in the temperture range investigated. Die molaren Wärmekapazitäten bei konstantem Druck von kleinen monoklinen α-Seleneinkristallen werden mittels einer Heizimpulstechnik im Temperaturbereich von 3 bis 300 K untersucht. Unterhalb 5 K befolgt die Molwärme als Funktion der Temperatur das Debyesche T3-Gesetz und ergibt eine Debyetemperature von θD = 128,3 K. Die Molwärme bei konstantem Volumen läßt sich im gesamten Temperaturbereich mittels einer Kombination von Debye- und Einsteintermen für die Frequenzverteilungsfunktion bezüglich der molekularen Ringstruktur von monoklinem Selen beschreiben. Darüberhinaus werden die Werte der thermodynamischen Funktionen berechnet. Die Ergebnisse dieser Untersuchung ergeben zusammen mit den von Chang und Bestful gegebenen Werten für trigonales Selen die Gibbssche freie Konversionsenergie. Die Berechnung zeigt, das monoklines α-Selen im untersuchten Temperaturbereich instabil ist." @default.
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- W2106577799 date "1978-09-16" @default.
- W2106577799 modified "2023-10-16" @default.
- W2106577799 title "Heat capacities and thermodynamic properties of α-monoclinic selenium in the range 3 to 300 K" @default.
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- W2106577799 doi "https://doi.org/10.1002/pssa.2210490106" @default.
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