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- W2106794508 abstract "Reaction of two new phosphorus ylides Ph 3 PCHCOC 10 H 7 (Y 1 ) and Ph 3 PCHCOC 4 H 3 S (Y 2 ) with mercury(II) halides and a previously reported ylide ( p -tolyl) 3 PCHCOOCH 2 Ph (Y 3 ) with CdCl 2 in equimolar ratios using methanol as solvent yielded binuclear complexes of the type [(Y).HgX 2 ] 2 (Y=Y 1 and Y 2 , X=Cl, Br and I) and a complex of [(Y 3 ).HgCl 2 ] 2 . The latter ylide reacts with Hg(NO 3 ) 2 .H 2 O in the same solvent with equimolar ratios to give a polynuclear complex [Hg(Y 3 )(NO 3 )(μ-NO 3 )] n . Also, the reaction between ylides and AgNO 3 in 1:2 molar ratios gave mononuclear complexes. Characterization of these products was carried out by elemental analysis, IR and multinuclear NMR techniques. Keywords: Phosphorus ylides, triphenylphosphine, mercury(II) nitrate, silver nitrate" @default.
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- W2106794508 date "2009-01-01" @default.
- W2106794508 modified "2023-09-28" @default.
- W2106794508 title "Synthesis and Characterization of Transition Metal (Hg(II), Ag(I) and Cd(II)) Complexes of Some New Phosphorus Ylides" @default.
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