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- W2106858832 abstract "Bei der thermischen Zersetzung 1,4-di(heteroallyl)substituierter Benzole H2CCHCH2XC6H4XCH2CHCH2 (X = O, S) in der Gasphase lassen sich PE-spektroskopisch para-Benzochinon, Monothio- oder Dithio-para-benzochinon sowie als Abgangsmolekül 1,5-Hexadien nachweisen. Zusätzlich gelingt es, die kurzlebigen Moleküle nach Kurzweg-Pyrolyse in einer Argon-Matrix bei 10 K zu isolieren und ihre UV- und IR-Spektren aufzunehmen. Ionisierungs- und Elektronenanregungsenergien sowie weitere Moleküleigenschaften des violetten 2,5-Cyclohexadien-1,4 dithions SC[HCCH]2CS stimmen mit vorausberechneten MNDO-Werten zufriedenstellend überein. Gasphase Reactions, 39. Photoelectron Spectroscopic Evidence and Matrix Isolation of Thio-para-benzoquinones The thermal decomposition of 1,4-di(heteroallyl) substituted benzenes H2CCHCH2XC6H4XCH2CHCH2 (X = O, S) in the gaseous phase produces para-benzoquinone, monothio or dithio para-benzoquinone, with 1,5-hexadiene as leaving molecule. The PE spectroscopic evidence can be further substantiated applying the shortway pyrolysis techniques to register also, after isolation in an argon matrix at 10 K, the UV and IR spectra of the short-lived species. Ionisation and electron excitation energies as well as other molecular properties of the violet 2,5-cyclohexadiene-1,4-dithione SC[HCCH]2CS correlate satisfactorily with precalculated MNDO values." @default.
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- W2106858832 date "1983-01-01" @default.
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- W2106858832 title "Gasphasen‐Reaktionen, 39. Photoelektronen‐spektroskopischer Nachweis und Matrix‐Isolierung von Thio‐ <i>para</i> ‐benzochinonen" @default.
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- W2106858832 doi "https://doi.org/10.1002/cber.19831160131" @default.
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