FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2106994208> ?p ?o ?g. }

• W2106994208 endingPage "5580" @default.
• W2106994208 startingPage "5572" @default.
• W2106994208 abstract "The reaction of [Mn(3)O(O(2)CMe)(6)(py)(3)] with the tripodal ligand H(3)thme (1,1,1-tris(hydroxymethyl)ethane) affords the enneanuclear complex [Mn(9)O(7)(O(2)CCH(3))(11)(thme)(py)(3)(H(2)O)(2)] 1.1MeCN.1Et(2)O. The metallic skeleton of complex 1 comprises a series of 10 edge-sharing triangles that describes part of an idealized icosahedron. Variable temperature direct current (dc) magnetic susceptibility data collected in the 1.8-300 K temperature range and in fields up to 5.5 T were fitted to give a spin ground state of S = (17)/(2) with an axial zero-field splitting parameter D = -0.29 cm(-)(1). Ac susceptibility studies indicate frequency-dependent out-of-phase signals below 4 K and an effective barrier for the relaxation of the magnetization of U(eff) = 27 K. Magnetic measurements of single crystals of 1 at low temperature show time- and temperature-dependent hysteresis loops which contain steps at regular intervals of field. Inelastic neutron scattering (INS) studies on complex 1 confirm the S = (17)/(2) ground state and analysis of the INS transitions within the zero-field split ground state leads to determination of the axial anisotropy, D = -0.249 cm(-)(1), and the crystal field parameter, B(4)(0) = 7(4) x 10(-)(6) cm(-)(1). Frequency domain magnetic resonance spectroscopy (FDMRS) determined the same parameters as D = -0.247 cm(-)(1) and B(4)(0) = 4.6 x 10(-)(6) cm(-)(1). DFT calculations are fully consistent with the experimental findings of two Mn(II) and four Mn(III) ions spin up and three Mn(IV) ions spin down resulting in the S = (17)/(2) spin ground state of the molecule, with D = -0.23 cm(-)(1) and U = 26.2 K." @default.
• W2106994208 created "2016-06-24" @default.
• W2106994208 creator A5008655226 @default.
• W2106994208 creator A5011491504 @default.
• W2106994208 creator A5021378883 @default.
• W2106994208 creator A5027075373 @default.
• W2106994208 creator A5047458591 @default.
• W2106994208 creator A5048702084 @default.
• W2106994208 creator A5053561663 @default.
• W2106994208 creator A5054818199 @default.
• W2106994208 creator A5061198429 @default.
• W2106994208 creator A5087387174 @default.
• W2106994208 creator A5090097086 @default.
• W2106994208 creator A5090568698 @default.
• W2106994208 date "2005-03-25" @default.
• W2106994208 modified "2023-10-18" @default.
• W2106994208 title "Studies of an Enneanuclear Manganese Single-Molecule Magnet" @default.
• W2106994208 cites W1950088148 @default.
• W2106994208 cites W1966756426 @default.
• W2106994208 cites W1967840024 @default.
• W2106994208 cites W1972335601 @default.
• W2106994208 cites W1981368803 @default.
• W2106994208 cites W1985887618 @default.
• W2106994208 cites W1993415455 @default.
• W2106994208 cites W2002762653 @default.
• W2106994208 cites W2005387079 @default.
• W2106994208 cites W2009046603 @default.
• W2106994208 cites W2019109263 @default.
• W2106994208 cites W2033683392 @default.
• W2106994208 cites W2039932887 @default.
• W2106994208 cites W2057614302 @default.
• W2106994208 cites W2080665513 @default.
• W2106994208 cites W2089740902 @default.
• W2106994208 cites W2090494419 @default.
• W2106994208 cites W2091097019 @default.
• W2106994208 cites W2106628973 @default.
• W2106994208 cites W2124263260 @default.
• W2106994208 cites W2214504069 @default.
• W2106994208 cites W2233591720 @default.
• W2106994208 cites W4232872022 @default.
• W2106994208 cites W4250016795 @default.
• W2106994208 doi "https://doi.org/10.1021/ja042302x" @default.
• W2106994208 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15826195" @default.
• W2106994208 hasPublicationYear "2005" @default.
• W2106994208 type Work @default.
• W2106994208 sameAs 2106994208 @default.
• W2106994208 citedByCount "89" @default.
• W2106994208 countsByYear W21069942082012 @default.
• W2106994208 countsByYear W21069942082013 @default.
• W2106994208 countsByYear W21069942082014 @default.
• W2106994208 countsByYear W21069942082015 @default.
• W2106994208 countsByYear W21069942082016 @default.
• W2106994208 countsByYear W21069942082017 @default.
• W2106994208 countsByYear W21069942082018 @default.
• W2106994208 countsByYear W21069942082019 @default.
• W2106994208 countsByYear W21069942082020 @default.
• W2106994208 countsByYear W21069942082021 @default.
• W2106994208 countsByYear W21069942082022 @default.
• W2106994208 countsByYear W21069942082023 @default.
• W2106994208 crossrefType "journal-article" @default.
• W2106994208 hasAuthorship W2106994208A5008655226 @default.
• W2106994208 hasAuthorship W2106994208A5011491504 @default.
• W2106994208 hasAuthorship W2106994208A5021378883 @default.
• W2106994208 hasAuthorship W2106994208A5027075373 @default.
• W2106994208 hasAuthorship W2106994208A5047458591 @default.
• W2106994208 hasAuthorship W2106994208A5048702084 @default.
• W2106994208 hasAuthorship W2106994208A5053561663 @default.
• W2106994208 hasAuthorship W2106994208A5054818199 @default.
• W2106994208 hasAuthorship W2106994208A5061198429 @default.
• W2106994208 hasAuthorship W2106994208A5087387174 @default.
• W2106994208 hasAuthorship W2106994208A5090097086 @default.
• W2106994208 hasAuthorship W2106994208A5090568698 @default.
• W2106994208 hasConcept C104015590 @default.
• W2106994208 hasConcept C115260700 @default.
• W2106994208 hasConcept C120665830 @default.
• W2106994208 hasConcept C121332964 @default.
• W2106994208 hasConcept C153294291 @default.
• W2106994208 hasConcept C15744967 @default.
• W2106994208 hasConcept C16889073 @default.
• W2106994208 hasConcept C178790620 @default.
• W2106994208 hasConcept C184779094 @default.
• W2106994208 hasConcept C185592680 @default.
• W2106994208 hasConcept C191486275 @default.
• W2106994208 hasConcept C26873012 @default.
• W2106994208 hasConcept C2776029896 @default.
• W2106994208 hasConcept C2777336399 @default.
• W2106994208 hasConcept C31198834 @default.
• W2106994208 hasConcept C32546565 @default.
• W2106994208 hasConcept C39353612 @default.
• W2106994208 hasConcept C46141821 @default.
• W2106994208 hasConcept C528890316 @default.
• W2106994208 hasConcept C62520636 @default.
• W2106994208 hasConcept C69523127 @default.
• W2106994208 hasConcept C77805123 @default.
• W2106994208 hasConcept C8010536 @default.
• W2106994208 hasConcept C85725439 @default.
• W2106994208 hasConceptScore W2106994208C104015590 @default.
• W2106994208 hasConceptScore W2106994208C115260700 @default.

• next