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• W2107084423 abstract "The direction and degree of 1,3-asymmetric induction have been evaluated in the addition of metal enolates and enolsilanes to aldehydes substituted at the β position with both polar (OR, OAc, Cl) and nonpolar (Me) substituents. A model for 1,3-asymmetric induction for polar addition processes such as the Mukaiyama aldol reaction is proposed to account for the documented trends in reaction diastereoselection for polar β-substituents." @default.
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• W2107084423 date "1994-11-01" @default.
• W2107084423 modified "2023-10-03" @default.
• W2107084423 title "1,3-Asymmetric induction in the aldol addition reactions of methyl ketone enolates and enolsilanes to β-substituted aldehydes. A model for chirality transfer" @default.
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• W2107084423 doi "https://doi.org/10.1016/s0040-4039(00)78430-9" @default.
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