Matches in SemOpenAlex for { <https://semopenalex.org/work/W2107089980> ?p ?o ?g. }
Showing items 1 to 47 of
47
with 100 items per page.
- W2107089980 endingPage "1921" @default.
- W2107089980 startingPage "1911" @default.
- W2107089980 abstract "α-Isobutyl-L-aspartate oligomers, Z-(α-i-Bu-Asp)2n–OEt (n = 1–5), where Z = benzyloxycarbonyl and OEt = ethyl ester, were prepared stepwise, and their conformation in solution was investigated by optical rotation, circular dichroism (CD), and NMR spectroscopy. The oligomers up to hexamer existed only in a disordered form. An ordered structure began to appear at octamer and decamer in chloroform and 2,2,2-trifluoroethanol. The ordered structure was more favorable for N-unprotected oligomers, H-(α-i-Bu-Asp)2n–OEt, in comparison with the corresponding Z-(α-i-Bu-Asp)2n–OEt. The effects of oligomer concentration and temperature on the structure were slightly observed. The most likely ordered structure was a β form caused by intramolecular association." @default.
- W2107089980 created "2016-06-24" @default.
- W2107089980 creator A5011116647 @default.
- W2107089980 creator A5037743382 @default.
- W2107089980 creator A5070398751 @default.
- W2107089980 date "1979-07-01" @default.
- W2107089980 modified "2023-09-24" @default.
- W2107089980 title "Poly(β-Amino acids). V. Synthesis and conformation of oligomeric α-isobutyl-L-aspartate" @default.
- W2107089980 doi "https://doi.org/10.1002/pol.1979.170170703" @default.
- W2107089980 hasPublicationYear "1979" @default.
- W2107089980 type Work @default.
- W2107089980 sameAs 2107089980 @default.
- W2107089980 citedByCount "6" @default.
- W2107089980 countsByYear W21070899802012 @default.
- W2107089980 crossrefType "journal-article" @default.
- W2107089980 hasAuthorship W2107089980A5011116647 @default.
- W2107089980 hasAuthorship W2107089980A5037743382 @default.
- W2107089980 hasAuthorship W2107089980A5070398751 @default.
- W2107089980 hasConcept C185592680 @default.
- W2107089980 hasConcept C515207424 @default.
- W2107089980 hasConcept C55493867 @default.
- W2107089980 hasConcept C71240020 @default.
- W2107089980 hasConceptScore W2107089980C185592680 @default.
- W2107089980 hasConceptScore W2107089980C515207424 @default.
- W2107089980 hasConceptScore W2107089980C55493867 @default.
- W2107089980 hasConceptScore W2107089980C71240020 @default.
- W2107089980 hasIssue "7" @default.
- W2107089980 hasLocation W21070899801 @default.
- W2107089980 hasOpenAccess W2107089980 @default.
- W2107089980 hasPrimaryLocation W21070899801 @default.
- W2107089980 hasRelatedWork W1927591950 @default.
- W2107089980 hasRelatedWork W1996140555 @default.
- W2107089980 hasRelatedWork W2044628742 @default.
- W2107089980 hasRelatedWork W2085061074 @default.
- W2107089980 hasRelatedWork W2125533158 @default.
- W2107089980 hasRelatedWork W2148960370 @default.
- W2107089980 hasRelatedWork W2149849649 @default.
- W2107089980 hasRelatedWork W2604165529 @default.
- W2107089980 hasRelatedWork W2951335092 @default.
- W2107089980 hasRelatedWork W4205670493 @default.
- W2107089980 hasVolume "17" @default.
- W2107089980 isParatext "false" @default.
- W2107089980 isRetracted "false" @default.
- W2107089980 magId "2107089980" @default.
- W2107089980 workType "article" @default.