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• W2107172649 abstract "A modified form of the Stockmayer potential for polar molecules is utilized to calculate: pair correlation functions in the limit of zero density, ordinary second virial coefficients, and dielectric second virial coefficients. The potential function is modified by allowing the dispersion–repulsion part of the energy to be that for a linear symmetric molecule whose potential energy is represented by Lennard‐Jones functions for the two “atoms” in the molecule interacting with the two “atoms” in neighboring molecules. This is combined with an ideal dipole–dipole energy to give the over‐all potential function. Changes in the statistical properties are calculated as a function of the molecular length, and results are presented which indicate that the ordinary second virial coefficients change by moderate amounts, but that the dielectric second virial coefficient is strikingly affected by the introduction of nonspherical molecular shapes." @default.
• W2107172649 created "2016-06-24" @default.
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• W2107172649 date "1969-01-15" @default.
• W2107172649 modified "2023-10-12" @default.
• W2107172649 title "Statistical Mechanics of Linear Molecules. IV. Nonspherical Polar Molecules" @default.
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• W2107172649 doi "https://doi.org/10.1063/1.1671115" @default.
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