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• W2107207333 abstract "rac-sec-Alkyl sulfate esters 1a–8a were resolved in low to excellent enantioselectivities with E-values up to >200 using whole cells of aerobically-grown hyperthermophilic sulfur-metabolizers, such as Sulfolobus solfataricus DSM 1617, Sulfolobus shibatae DSM 5389 and, most notably, Sulfolobus acidocaldarius DSM 639. Significantly enhanced selectivities were obtained using cells grown on sucrose-enriched Brock-medium. The stereochemical course of this biohydrolysis was shown to proceed with strict inversion of configuration, thus the preferred (R)-enantiomers were converted into the corresponding (S)-sec-alcohols to furnish a homochiral product mixture." @default.
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• W2107207333 date "2005-01-01" @default.
• W2107207333 modified "2023-10-18" @default.
• W2107207333 title "Highly enantioselective stereo-inverting sec-alkylsulfatase activity of hyperthermophilic Archaea" @default.
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• W2107207333 doi "https://doi.org/10.1039/b504883d" @default.
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